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Marine gas hydrate inventory: preliminary results of ODP Leg 164 and implications for gas venting and slumping associated with the Blake Ridge gas hydrate field
Paull, C.K.; Borowski, W.S.; Rodriguez, N.M. (1998). Marine gas hydrate inventory: preliminary results of ODP Leg 164 and implications for gas venting and slumping associated with the Blake Ridge gas hydrate field, in: Henriet, J.-P. et al. Gas hydrates: relevance to world margin stability and climate change. Geological Society Special Publication, 137: pp. 153-160. https://dx.doi.org/10.1144/GSL.SP.1998.137.01.12
In: Henriet, J.-P.; Mienert, J. (1998). Gas hydrates: Relevance to world margin stability and climate change. Geological Society Special Publication, 137. The Geological Society: London. ISBN 1-86239-010-X. 338 pp., more
In: Hartley, A.J. et al. (Ed.) Geological Society Special Publication. Geological Society of London: Oxford; London; Edinburgh; Boston, Mass.; Carlton, Vic.. ISSN 0305-8719; e-ISSN 2041-4927, more

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Keywords
    Chemical compounds > Organic compounds > Hydrocarbons > Gas hydrates
    Chemical compounds > Organic compounds > Hydrocarbons > Saturated hydrocarbons > Acyclic hydrocarbons > Methane
    Documents > Catalogues > Inventories
    Gas venting
    Transport > Sediment transport > Mass gravity transport (sediments) > Slumping
    ASW, Blake Ridge [Marine Regions]
    Marine/Coastal

Authors  Top 
  • Paull, C.K.
  • Borowski, W.S.
  • Rodriguez, N.M.

Abstract
    Deep ODP holes on the Blake Ridge (sites 994, 995 and 997; Leg 164) show that sediments within the interval ∼200–450 metres below sea floor (mbsf) contain 1–4% gas hydrate based on interstitial geochemistry, pressure core samples, well logs and borehole seismic data. In addition, a considerable methane gas reservoir also exists below the gas hydrate stability zone in the form of free and dissolved methane. Addition of methane from these deep reservoirs to overlying ocean water (and ultimately to the atmosphere) could have profound geological, geochemical and climatic effects. Pervasive flux of methane to the sea floor via diffusion is unlikely because methane is almost completely consumed by reaction with sulphate at the sulphate-methane interface. Further, sulphate and 87Sr/86Sr profiles suggest that upward advection of potential methane-containing fluids is also unlikely. However, point sources for methane advection to the sea floor do occur. Active methane transport along faults occurs at Site 996, and the methane 13C isotopic signature indicates derivation from the gas hydrate-bearing and free gas zones below. 14C data from sediments indicate that the frequency of sediment slumping on the Blake Ridge is higher during the sea-level lowstand associated with the last ice age. Whereas there is no direct evidence that methane exchange is associated with slump events, nor that gas hydrates are necessarily related to the increased slumping frequency, the association between slumps and faults suggest that the amounts of gas escape should be greater during sea-level lowstands.

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